Ideal Gas Thermodynamic Properties of Ch, A+, +, F4, Halomethanes

By Kudchadker, Shanti A.

Book Id: WPLBN0000661559
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Reproduction Date: 2005

Title:	Ideal Gas Thermodynamic Properties of Ch, A+, +, F4, Halomethanes
Author:	Kudchadker, Shanti A.
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Language:	English
Subject:	Technology., Reference materials, Technology and literature
Collections:	Techonology eBook Collection
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Citation APA MLA Chicago A. Kudchadke, B. S. (n.d.). Ideal Gas Thermodynamic Properties of Ch, A+, +, F4, Halomethanes. Retrieved from http://www.gutenberg.us/

Description
Technical Reference Publication

Excerpt
Introduction: This work is the continuation of calculations of the thermodynamic properties of bromo- and iodomethanes 111. For this purpose, a systematic literature survey complete up to 1976 was carried out on vibrational frequencies, structural parameters and enthalpies of formation of mixed halomethanes, BraIb(X=H, F, Cl). Out of forty seven compounds of this type the vibrational frequencies were available for only twenty one compounds. The structural data and gaseous enthalpies of formation at 298.15 E were available for very few compounds. Hence we had to estimate them for most of the compounds in order to calculate their thermodynamic properties.

Table of Contents
Contents Page List of Tables 1. Introduction . . . . . . . . . . . . . 1286 Table page 1.1. Scope and Objectives . . . . . . . 1286 1. L XCZ in Various C&Z Compounds . . 1287 le2. Data. . . . . . . . a * * 2. Structural Parameters for Halomethanes 1288 1.3 Vibrational Frequencies . . . . . . 1287 1.4. Enthalpy of Formation . . . . . . 1287 3. Structural Parameters and Moments of 2. Fluorobromomethane (CH2FBr) 1291 . . . . Inertia for CX3Y. a.nd. C.X.zY.2.T y.p.e M. i.xe.d 3. Chlorobromomethane (CH,CIBr) 1291 . . . . Halomethanes 1288 4. Chloroiodomethane (CH2C11) . . . . . . 1291 4. Parameters and 5. Bromoiodomethane (CH2BrI) . . . . . . 1293 Inertia for CX2YZ Type Mixed Halometh- 6. Difluorobromomethane (CHF2Br) . . . . 1293 anes. . . . . . . . . . . . . . . . . 1288 7. Fluorochlorobromomethane (CHFClBr) . 1293 5. Vibrational Frequencies of Mixed Halo- 8. Fluorodibromomethane (CEEBr2) . . . . 1295 methanes. . . . . . . . . . . . . . . 1289 9. Dichlorobromomethane (CHC1,Br). . . . 1295 5a. Maximum Uncertainties in the Vibrational 10. Chlorodibromomethane (CHC1Br2). . . . 1295 Frequencies and Derived Thermodynamic 11. Trifluorobromomethane (cF~B~) . . . . 1297 Properties at 100- 1500 K . . . . . . . 1289 12. Trifluoroiodomethane (CFJ) . . . . . . 1297 6. Contributions to HfO (g,298)i n kcal mol-'. 1290 13. Difluorochlorobromomethane (CF2ClBr) . 1298 7. mjo (g,298) of ~~l~~~~~~~~~ . . . . . 1290 14. Difluorodibromomethane (CF2Br2) . . . . 1298 15. Difluorodiiodomethane (CF212) 1300 . . . . . 8. Ideal Gas Thermodynamic Prope.rti.es. o.f 16. Fluorodichlorobromomethane (CFC1,Br) . 1300 Fluorobromomethane (CH2FBr). 1292 17. Fluorochlorodibromomethane (CFC1Br2) . 1300 9- Idea' Gas Thermodynamic Properties 18. Fluorotribromomethane (CFBr3) . . . . 1302 Chlorobromomethane (CH2ClBr) . . . . 1292 19. Trichlorobromomethane (CC13Br) . . . . 1302 10. Ideal Gas Thermodynamic Properties of 20. Trichloroiodomethane (CC1,I) . . . . . 1303 Chloroiodomethane (CH2C11) . . . . . . 1293 21. Dichlorodibromomethane (CC12Br2). . . . 1304 11. Ideal Gas Thermodynamic Properties of 22. Chlorotribromomethane (CClBr3) . . . . 1304 Bromoiodomethane (CH2BrI) . . . . . . 1294 23. Comparison - - . - - . - . - . 1305 12. Ideal Gas Thermodynamic Properties of Acknowledgements . . . . . . . . . . 1306 Diiluorobromomethane (CHF2Br) . . . . 1294 References . . . . . . . . . . . . . . 1036 13. Ideal Gas Thermodynamic Properties of @ 1978 by the U.S. Secretary of Commerce on behalf of the Fluorochlorobromomethane (CHE'CIB~) . 1295 United States. This copyright is assigned to the American 14. Ideal Gas of Institute of Physics and the American Chemical Society. Fluorodibromomethane (CHFBr2) . . . . 1296 J. Phys. Chem. Ref. Data, Vol. 7, No. 4, 1978