Thermodynamic Properties of Alkali Metal Hydroxides. Part 1. Lithium and Sodium Hydroxides

By Gurvich, L. V.

Book Id: WPLBN0000659906
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Reproduction Date: 2005

Title:	Thermodynamic Properties of Alkali Metal Hydroxides. Part 1. Lithium and Sodium Hydroxides
Author:	Gurvich, L. V.
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Language:	English
Subject:	Technology., Reference materials, Technology and literature
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Citation APA MLA Chicago Gurvich, L. (n.d.). Thermodynamic Properties of Alkali Metal Hydroxides. Part 1. Lithium and Sodium Hydroxides. Retrieved from http://www.gutenberg.us/

Description
Technical Reference Publication

Excerpt
Introduction: The thermodynamic properties of condensed and gaseous lithium, sodium, potassium, rubidium, and cesium hydroxides in standard states have been reevaluated. This activity was stimulated by the existence of new data since the time of publication of four critical reviews containing analogous information.

Table of Contents
Contents 1. Introduction.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1213 3.2.4. Appendix. Tables of Experimental and 1.1. References for the Introduction. . . . . . . . . . . . 1214 Evaluated Data for Na202H2(g).. ...... 1269 2. Lithium Hydroxide.. ........................ 1215 4. References for Lithium and Sodium Hydroxides.. 1271 2.1. Hydroxide in Condensed Phases.. .. 1215 5. Recommendations for Future Measurements. .... 1276 2.1.1. Heat Capacity and Enthalpy Measurements. . . . . . . . . . . . . . . . . . . . . . 1215 2.1.2. Enthalpy of Formation of LiOH(cr). .... 1219 2.1.3. Appendix. Tables of Experimental and Evaluated Data. . . . . . . . . . . . . . . . . . . . . 1222 2.2. Lithium Hydroxide in Gaseous Phase.. ..... 1226 2.2.1. Lithium Hydroxide Monomer. . . . . . . . . 1226 2.2.2. Appendix. Tables of Experimental and Evaluated Data for LiOH(g). . . . . . . . . . . 1237 2.2.3. Lithium Hydroxide Dimer. . . . . . . . . . . . 1240 2.2.4. Appendix. Tables of Experimental and Evaluated Data for Li202H2(g). . . . . . . . 1244 Sodium Hydroxide. . . . . . . . . . . . . . . . . . . . . . . . . . 1246 3.1. Sodium Hydroxide in Condensed Phases. ... 1246 3.1.1. Heat Capacity and Enthalpy Measurements.. . . . . . . . . . . . . . . . . . . . . 1246 3.1.2. Enthalpy of Formation of NaOH(cr). ... 1253 3.1.3. Appc~ldin.T dblcs uC Enpc~ilr~c~~~lIdIl J Evaluated Data for NaOH(cr). . . . . . . . . 1255 3.2. Sodium Hydroxide in Gaseous Phase. . . . . . . 1260 3.2.1. Sodium Hydroxide Monomer. ......... 1260 3.2.2. Appendix. Tables of Experimental and Evaluated Data for NaOH(g). . . . . . . . . . 1266 3.2.3. Sodium Hydroxide Dimer. . . . . . . . . . . . 1268 01996 by the U.S. Secretary of Commerce on behalf of the United States. All rights reserved. This copyright is ass~gnedt o the American Institute of Physics and the American Chemical Society. Reprints available from ACS; see Reprints List at back of issue. List of Tables 1-1. Crystal structure and lattice parameters of the alkali metal hydroxides. . . . . . . . . . . . . . . . . . . . . 1214 2- 1. Experimental heat capacity values of LiOH [5OBAU/JOH]. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1222 2-2. Experimental enthalpy values HO (T) - HO (298.15 K) of LiOH [54POW/BLA]. . . . . . . . . . 1222 2-3. Experimental enthalpy values HO (T) - HO (298.15 K) af LiOH [55SHO/COH]. . . . . . . . . . . 1223 2-4. Comparison of the heat capacity, enthalpy, ent~upy,a nd entllalpy uI Iu~lllaliulv~a lues IUI LiOH(cr). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1223 2-5. Temperature of fusion of LiOH. . . . . . . . . . . . . . 1223 2-6. Enthalpy of fusion of LiOH.. . . . . . . . . . . . . . . . 1224 2-7. Thermal functions of LiOH(cr) below 298.15 K.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1224 2-8. Differences (in J K- mol-I) between the thermal functions of LiOH(cr and liq) calculated in the present work and in [82GURNEY] and in [85CHA/DAV]. . . . . . . . . 1224 2-9. The enthalpy of formation of LiOH(cr) from measurements of the enthalpy of solution of lithium hydroxide in water. . . . . . . . . . . . . . . . . . 1224 2-10. The enthalpy of formation of LiOH(cr) based on dissociation pressure measurements for reaction 2LiOH(cr,liq)= Li,O(cr) +H20(g) ( k m~o l- I ) . . . . . . . . . . . . . . . . . . . . . . . 1224 2- 1 1. Experimental data on the equilibrium constants (Klatm) at different temperatures (TIK) for the 0047-2689/96/25(4)/1211166/$18.00 1211 J. Phys. Chem. Ref. Data, Vol. 25, No. 4, 1996