In electromagnetism, charge density is a measure of electric charge per unit volume of space, in one, two or three dimensions. More specifically: the linear, surface, or volume charge density is the amount of electric charge per unit length, surface area, or volume, respectively. The respective SI units are C·m^{−1}, C·m^{−2} or C·m^{−3}.^{[1]}
Like any density, charge density can depend on position, but charge and thus charge density can be negative. It should not be confused with the charge carrier density, the number of charge carriers (e.g. electrons, ions) in a material per unit volume, not including the actual charge on the carriers
In chemistry, it can refer to the charge distribution over the volume of a particle; such as a molecule, atom or ion. Therefore, a lithium cation will carry a higher charge density than a sodium cation due to the lithium cation's having a smaller ionic radius, even though sodium has more protons (11) than lithium (3).
Definitions
Continuous charges
Continuous charge distribution. The volume charge density ρ is the amount of charge per unit volume (cube), surface charge density σ is amount per unit surface area (circle) with outward
unit normal n̂,
d is the
dipole moment between two point charges, the volume density of these is the
polarization density P.
Position vector r is a point to calculate the
electric field;
r′ is a point in the charged object.
Following are the definitions for continuous charge distributions.^{[2]}^{[3]}
The linear charge density is the ratio of an infinitesimal electric charge dQ (SI unit: C) to an infinitesimal line element,

\lambda_q = \frac{d Q}{d \ell}\,,\quad
similarly the surface charge density uses a surface area element dS

\sigma_q = \frac{d Q}{d S}\,,\quad
and the volume charge density uses a volume element dV

\rho_q =\frac{d Q}{d V}\,,\quad
Integrating the definitions gives the total charge Q of a region according to line integral of the linear charge density λ_{q}(r) over a line or 1d curve C,

Q=\int\limits_L \lambda_q(\bold{r}) \,d\ell
similarly a surface integral of the surface charge density σ_{q}(r) over a surface S,

Q=\int\limits_S \sigma_q(\bold{r}) \,dS
and a volume integral of the volume charge density ρ_{q}(r) over a volume V,

Q=\int\limits_V \rho_q(\bold{r}) \,dV
where the subscript q is to clarify that the density is for electric charge, not other densities like mass density, number density, probability density, and prevent conflict with the many other uses of λ, σ, ρ in electromagnetism for wavelength, electrical resistivity and conductivity.
Within the context of electromagnetism, the subscripts are usually dropped for simplicity: λ, σ, ρ. Other notations may include: ρ, ρ_{s}, ρ_{v}, ρ_{L}, ρ_{S}, ρ_{V} etc.
Average charge densities
The total charge divided by the length, surface area, or volume will be the average charge densities:

\langle\lambda_q \rangle = \frac{Q}{\ell}\,,\quad \langle\sigma_q\rangle = \frac{Q}{S}\,,\quad\langle\rho_q\rangle = \frac{Q}{V}\,.
Free, bound and total charge
In dielectric materials, the total charge of an object can separate into "free" and "bound" charges.
Bound charges set up electric dipoles in response to an applied electric field E, and polarize other nearby dipoles tending to line them up, the net accumulation of charge from the orientation of the dipoles is the bound charge. They are called bound because they cannot be removed: in the dielectric material the charges are the electrons bound to the nuclei.^{[3]}
Free charges are the excess charges which can move into electrostatic equilibrium, i.e. when the charges are not moving and the resultant electric field is independent of time, or constitute electric currents.^{[2]}
Total charge densities
In terms of volume charges densities, the total charge density is:

\rho = \rho_f + \rho_b\,.
as for surface charge densities:

\sigma = \sigma_f + \sigma_b\,.
where subscripts "f" and "b" denote "free" and "bound" respectively.
Bound charge
The bound surface charge is the charge piledup at the surface of the dielectric, given by the dipole moment perpendicular to the surface:^{[3]}

q_b = \frac{\bold{d} \cdot\mathbf{\hat{n}}}{\bold{s}}
where s is the separation between the point charges constituting the dipole. Taking infinitesimals:

d q_b = \frac{d\bold{d}}{\bold{s}}\cdot\mathbf{\hat{n}}
and dividing by the differential surface element dS gives the bound surface charge density:

\sigma_b = \frac{d q_b}{d S} = \frac{d\bold{d}}{\bold{s} dS} \cdot\mathbf{\hat{n}} = \frac{d\bold{d}}{dV} \cdot\mathbf{\hat{n}} = \bold{P} \cdot\mathbf{\hat{n}}\,.
where P is the polarization density, i.e. density of electric dipole moments within the material, and dV is the differential volume element.
Using the divergence theorem, the bound volume charge density within the material is
q_b = \iiint \rho_b dV = {\scriptstyle S}\bold{P} \cdot \mathbf{\hat{n}} dS = \iiint\nabla\cdot\mathbf{P}dV
hence:

\rho_b =  \nabla\cdot\mathbf{P}\,.
The negative sign arises due to the opposite signs on the charges in the dipoles, one end is within the volume of the object, the other at the surface.
A more rigorous derivation is given below.^{[3]}

Free charge density
The free charge density serves as a useful simplification in Gauss's law for electricity; the volume integral of it is the free charge enclosed in a charged object  equal to the net flux of the electric displacement field D emerging from the object:

\Phi_D = {\scriptstyle S}\bold{D} \cdot\bold{\hat{n}}dS = \iiint \rho_f dV
See Maxwell's equations and constitutive relation for more details.
Homogeneous charge density
For the special case of a homogeneous charge density ρ_{0}, independent of position i.e. constant throughout the region of the material, the equation simplifies to:

Q=V\cdot \rho_0.
The proof of this is immediate. Start with the definition of the charge of any volume:

Q=\int\limits_V \rho_q(\bold{r}) \,dV.
Then, by definition of homogeneity, ρ_{q}(r) is a constant denoted by ρ_{q, 0} (to differ between the constant and nonconstant densities), and so by the properties of an integral can be pulled outside of the integral resulting in:

Q=\rho_{q,0} \int\limits_V \,dV = \rho_0 V
so,

Q=V \cdot \rho_{q,0}.
The equivalent proofs for linear charge density and surface charge density follow the same arguments as above.
Discrete charges
For a single point charge q at position r_{0} inside a region of 3d space R, like an electron, the volume charge density can be expressed by the Dirac delta function:

\rho_q(\bold{r}) = q \delta(\mathbf{r}  \mathbf{r}_0)
where r is the position to calculate the charge.
As always, the integral of the charge density over a region of space is the charge contained in that region. The delta function has the sifting property for any function f:

\int_R d^3 \mathbf{r} f(\mathbf{r})\delta(\mathbf{r}  \mathbf{r}_0) = f(\mathbf{r}_0)
so the delta function ensures that when the charge density is integrated over R, the total charge in R is q:

Q =\int_R d^3 \mathbf{r} \, \rho_q =\int_R d^3 \mathbf{r} \, q \delta(\mathbf{r}  \mathbf{r}_0) = q \int_R d^3 \mathbf{r} \, \delta(\mathbf{r}  \mathbf{r}_0) = q
This can be extended to N discrete pointlike charge carriers. The charge density of the system at a point r is a sum of the charge densities for each charge q_{i} at position r_{i}, where i = 1, 2, ..., N:

\rho_q(\bold{r})=\sum_{i=1}^N\ q_i\delta(\mathbf{r}  \mathbf{r}_i)\,\!
The delta function for each charge q_{i} in the sum, δ(r − r_{i}), ensures the integral of charge density over R returns the total charge in R:

Q=\int_R d^3 \mathbf{r} \sum_{i=1}^N\ q_i\delta(\mathbf{r}  \mathbf{r}_i) = \sum_{i=1}^N\ q_i \int_R d^3 \mathbf{r} \delta(\mathbf{r}  \mathbf{r}_i) = \sum_{i=1}^N\ q_i
If all charge carriers have the same charge q (for electrons q = −e, the electron charge) the charge density can be expressed through the number of charge carriers per unit volume, n(r), by

\rho_q(\bold{r})= q n(\mathbf{r})\,.
Similar equations are used for the linear and surface charge densities.
Charge density in special relativity
In special relativity, the length of a segment of wire depends on velocity of observer because of length contraction, so charge density will also depend on velocity. Anthony French^{[4]} has described how the magnetic field force of a currentbearing wire arises from this relative charge density. He used (p 260) a Minkowski diagram to show "how a neutral currentbearing wire appears to carry a net charge density as observed in a moving frame." When a charge density is measured in a moving frame of reference it is called proper charge density.^{[5]}^{[6]}^{[7]}
It turns out the charge density ρ and current density J transform together as a four current vector under Lorentz transformations.
Charge density in quantum mechanics
In quantum mechanics, charge density ρ_{q} is related to wavefunction ψ(r) by the equation

\rho_q(\bold{r}) = q \psi(\mathbf r)^2
where q is the charge of the particle and ψ(r)^{2} = ψ*(r)ψ(r) is the probability density function i.e. probability per unit volume of a particle located at r.
When the wavefunction is normalized  the average charge in the region r ∈ R is

Q= \int_R q \psi(\mathbf r)^2 \, {\rm d}^3 \bold{r}
where d^{3}r is the integration measure over 3d position space.
Application
The charge density appears in the continuity equation for electric current, also in Maxwell's Equations. It is the principal source term of the electromagnetic field, when the charge distribution moves this corresponds to a current density.
See also
References

^

^ ^{a} ^{b}

^ ^{a} ^{b} ^{c} ^{d}

^ A. French (1968) Special Relativity, chapter 8 Relativity and electricity, pp 229–65, W. W. Norton.

^ Richard A. Mould (2001) Basic Relativity, §62 Lorentz force, Springer Science & Business Media ISBN 0387952101

^ Derek F. Lawden (2012) An Introduction to Tensor Calculus: Relativity and Cosmology, page 74, Courier Corporation ISBN 0486132145

^ Jack Vanderlinde (2006) Classical Electromagnetic Theory, § 11.1 The Fourpotential and Coulomb’s Law, page 314, Springer Science & Business Media ISBN 1402027001
External links

[1]  Spatial charge distributions
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